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Biogas Upgradation: CO₂ Removal from Biogas

3 min read

As we have already explained in our earlier blog titled Adsorption: The Future of Gas Separation – A Clean Technology, there are vast applications for the usage of absorption technology in today’s world.

In this blog, we will talk about one of the new applications of absorption technology in the field of biogas upgradation.

Biogas upgradation is a vital process that transforms raw biogas into a high-calorific-value fuel by removing undesirable components such as carbon dioxide (CO₂) and hydrogen sulfide (H₂S). This article delves into the composition of biogas, the technical aspects of Pressure Swing Adsorption (PSA) technology for CO₂ removal, and advancements in Vacuum Pressure Swing Adsorption (VPSA). Finally, we provide insights into the future potential of adsorption technologies for biogas upgradation.

Composition of Biogas

Biogas derived from food waste contains approximately 30% CO₂, which significantly lowers its calorific value, rendering it inefficient as a fuel. To enhance its usability, CO₂ must be reduced to concentrations below 5%.

Pressure Swing Adsorption (PSA) Technology

Principle of Operation

PSA technology leverages molecular sieves to separate CO₂ from CH₄ in biogas. The process involves the following steps:

  1. Compression: Raw biogas at a low pressure of ~0.02 barg is compressed to 6-8 barg.
  2. H₂S Removal: Silica beds adsorb H₂S from the biogas stream.
  3. Drying: A dryer removes water vapour to prevent operational issues.
  4. Adsorption: Compressed biogas passes through PSA beds containing molecular sieves. CO₂ is selectively adsorbed, allowing CH₄ (at >95% purity) to pass as the product gas.
  5. Regeneration: Adsorbed CO₂ is released during the depressurization of the PSA bed, restoring the sieves for subsequent cycles.
Process Efficiency
  • Methane Recovery: PSA achieves a methane recovery rate of approximately 95-98%.
  • Automation: Twin PSA beds enable continuous operation, with one bed in adsorption mode while the other regenerates, controlled via a PLC system.
  • Output: High-purity CH₄ is stored in tanks, with quality checks for CO₂ concentration before distribution.

Environmental Considerations

The released CO₂ during regeneration is typically vented into the atmosphere. However, ongoing research aims to capture and store this CO₂ in high-pressure cylinders for industrial applications, reducing greenhouse gas emissions.

Vacuum Pressure Swing Adsorption (VPSA)

 Advantages over PSA

VPSA operates similarly to PSA but incorporates vacuum conditions during regeneration. This reduces energy consumption and increases methane recovery. Key distinctions include:

  • Energy Efficiency: Lower operating pressures reduce power requirements.
  • Initial Investment: VPSA systems have higher upfront costs compared to PSA.

Applications

VPSA is particularly suited for installations where operational efficiency and long-term cost savings outweigh initial capital expenses.

Challenges and Future Prospects

Challenges

  1. Capital Costs: High initial investment for VPSA systems.
  2. Energy Consumption: PSA processes require significant power for compression.
  3. CO₂ Utilization: Current technologies often release CO₂ without repurposing it.

Future Directions

  • Advanced Adsorbents: Development of higher-capacity molecular sieves to improve efficiency.
  • Integrated Systems: Combining PSA with CO₂ capture technologies to create a closed-loop system.
  • Research and Development: Innovations in adsorption materials and system design to reduce costs and improve sustainability.

Conclusion

Biogas upgradation through PSA and VPSA technologies represents a sustainable approach to converting waste into renewable energy. With advancements in adsorption technology and CO₂ utilization methods, the potential for biogas as a clean energy source continues to expand.

References

  1. Absstem Technologies. (2024). Adsorption: The Future of Gas Separation – A Clean Technology.

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